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picture1_Material Ppt 77471 | Basic Theory


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File: Material Ppt 77471 | Basic Theory
nomenclature gel permeation chromatography gpc size exclusion chromatography sec gel filtration chromatography gfc types of liquid chromatography interactive adsorption partition ion exchange etc non interactive gpc sec gfc why do ...

icon picture PPT Filetype Power Point PPT | Posted on 03 Sep 2022 | 3 years ago
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                              Nomenclature
                    Gel Permeation Chromatography GPC
                    Size Exclusion Chromatography   SEC
                    Gel Filtration Chromatography   GFC
            Types of Liquid Chromatography
           Interactive adsorption, partition, ion exchange, etc
                Non-interactive GPC, SEC, GFC
                                Why do GPC ?
       GPC is the only technique for                MWD determined by GPC
          characterising polymer molecular 
          weight distribution 
       As Mw/Mn decreases the strength and 
          toughness of the polymer increases
       However as Mw/Mn decreases the 
          polymer becomes more difficult to 
          process
       GPC provides key information to 
          predict the processability and material 
          properties of a polymer
      Size Exclusion Mechanism
            GPC Separation Mechanism
    Polymer is prepared as a dilute solution in the 
    eluent and injected into the system
    The  GPC  column  is  packed  with  porous 
    beads of controlled porosity and particle size
    Large molecules are not able to permeate all 
    of  the  pores  and  have  a  shorter  residence 
    time in the column
    Small  molecules  permeate  deep  into  the 
    porous matrix and have a long residence time 
    in the column
    Polymer molecules are separated according 
    to molecular size, eluting largest first, smallest 
    last
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...Nomenclature gel permeation chromatography gpc size exclusion sec filtration gfc types of liquid interactive adsorption partition ion exchange etc non why do is the only technique for mwd determined by characterising polymer molecular weight distribution as mw mn decreases strength and toughness increases however becomes more difficult to process provides key information predict processability material properties a mechanism separation prepared dilute solution in eluent injected into system column packed with porous beads controlled porosity particle large molecules are not able permeate all pores have shorter residence time small deep matrix long separated according eluting largest first smallest last...

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